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我國大氣中揮發性有機物監測與控制現狀分析

作者:ylhb 來源: 日期:2017-12-04 11:11:28 人氣:25

摘要:梳理了我國現有的揮發性有機物(VOCs)監測與控制相關的政策標準,介紹了環境空氣中VOCs和污染源VOCs排放的監測情況,指出我國亟需全面開展環境空氣中的VOCs的例行監測,各地需根據實際情況確定涉VOCs的重點監控企業名錄并盡快開展污染源監督性監測,同時應盡快建立VOCs監測方法標準體系。

前言

       HUIFAXINGYOUJIHUAHEWU(VolatileOrganicCompounds,VOCs)SHIZHIRONGDIANDIYUSHIWEN、FEIDIANFANWEIZAI50~260℃ZHIJIANDEHUIFAXINGYOUJIWUDEZONGCHENG。TONGCHANGFENWEIBAOKUOWANJING、XIJING、GUIJING、FANGXIANGJINGDEFEIJIAWANTANQINGHUAHEWU(NMHCs),BAOKUOQUAN、TONG、CHUN、MIDENGDEHANYANGYOUJIHUAHEWU(OVOCs),LUDAIJING,HANDANHUAHEWU,HANLIUHUAHEWUDENGJIDALEI。VOCsSHIDAQIZHONGYILEIZHONGYAODEQITAIWURANWU,VOCsBUJINDUIRENTIJIANKANGHESHENGTAIHUANJINGDENGYOUZHIJIEYINGXIANG,HUANKEYITONGGUOCANYUDAQIGUANGHUAXUEFANYINGSHENGCHENGERCIWURANWU,RUCHOUYANG(O3)、GUOYANGYIXIANXIAOSUANZHIHEYOUJIQIRONGJIAODENG,YINCIVOCsSHIO3HEPM2.5DEZHONGYAOQIANTIWUZHIYI。CONG2013NIANYILAI,WOGUOGEZHIXIASHI、SHENGHUICHENGSHI、JIHUADANLIESHIYIJIJINGJINJI、CHANGSANJIAO、ZHUSANJIAODENGZHONGDIANQUYUCHENGSHI,KAISHIANZHAOKONGQIZHILIANGXINBIAOZHUNDEYAOQIUKAIZHANLEBAOKUOO3HEPM2.5ZAINEIDE6XIANGWURANWUDEJIANCE,XINBIAOZHUNSHISHIYILAIDEJIANCEJIEGUOBIAOMING,WOGUOZHONGDIANQUYUO3HEPM2.5CHAOBIAOJIAOWEIPUBIAN。HUANBAOBUGONGBUDEZHONGGUOHUANJINGZHILIANGZHUANGKUANGGONGBAOXIANSHI,2015NIANDIYIPISHISHIXINBIAOZHUNDE74GECHENGSHIDABIAOTIANSHUBILIPINGJUNWEI71.2%,PINGJUNCHAOBIAOTIANSHUBILIWEI28.8%,CHAOBIAOTIANSHUZHONGYIPM2.5WEISHOUYAOWURANWUDEZHAN62.7%,YIO3WEISHOUYAOWURANWUDEZHAN24.9%,YIPM10WEISHOUYAOWURANWUDEZHAN10.9%,YIO3WEISHOUYAOWURANWUDEBILIYIJINGCHAOGUOLEPM10,PM2.5HEO3YICHENGWEIYINGXIANGWOGUOCHENGSHIHUANJINGKONGQIZHILIANGDESHOUYAOWURANWU。MUQIANZAIGUOJISHANG,O3TONGYANGSHIYINGXIANGXUDUOFADAGUOJIAHUANJINGKONGQIZHILIANGDEZHONGYAOWURANWU,MEIGUOEPAGONGBUDE2015NIANMEIGUOKONGQIZHILIANGXIANZHUANGHEQUSHIXIANSHI,2015NIANQUANMEIGUOGEDIANWEIO38XIAOSHIPINGJUNNONGDUWEI67ppb,QIDI90BAIFENWEISHUDADAO77ppb,BIAOMINGYOUCHAOGUO10%DEZHANDIANO3NONGDURENGRANWUFADADAOMEIGUOHUANJINGKONGQIZHILIANGBIAOZHUNYAOQIU(75ppb)。YINCI,VOCsZUOWEIPM2.5HEO3ZHONGYAOQIANTIWUYERIYISHOUDAORENMENDEGUANZHU,CHENGWEIGUONEIWAIHUANJINGLINGYUYANJIUDEJIAODIAN。BENWENJIEHEWOGUOHUANJINGGUANLIQINGKUANG,DUIVOCsJIANCEYUKONGZHIXIANZHUANGJINXINGLEYANJIUYUTANTAO。

我國VOCs監測與控制相關政策及標準

手机捕鱼        JINNIANLAI,SUIZHUDUIVOCsDEGUANZHUDUYUELAIYUEGAO,WOGUOLUXUBANBULEVOCsWURANKONGZHIXIANGGUANDEFAGUIZHENGCE。2015NIANQUANGUORENDACHANGWEIHUIDUI《DAQIWURANFANGZHIFA》JINXINGLEXIUDING,XIUDINGBANZHONGSHOUCIJIANGVOCsNARUJIANGUANFANWEI,TICHUTUIXINGQUYUDAQIWURANLIANHEFANGZHI,DUIVOCsDENGDAQIWURANWUHEWENSHIQITISHISHIXIETONGKONGZHI。DUISHENGCHAN、JINKOU、XIAOSHOUHESHIYONGHANVOCsDEYUANCAILIAOHECHANPIN、DUICHANSHENGHANVOCsFEIQIDESHENGCHANHEFUWUHUODONG,DUIGONGYETUZHUANGQIYESHIYONGHANVOCsDETULIAO,DUISHIYOU、HUAGONGYIJIQITASHENGCHANHESHIYONGYOUJIRONGJIDEQIYE,DUICHUYOUCHUQIKU、JIAYOUJIAQIZHAN、YUANYOUCHENGPINYOUMATOU、YUANYOUCHENGPINYOUYUNSHUCHUANBOHEYOUGUANCHE、QIGUANCHESHEJIVOCsPAIFANGDEGEHUANJIEDEHUANJINGBAOHUYAOQIUJINXINGLEMINGQUEGUIDING。2011NIANGUOWUYUANBANBULE《GUOJIAHUANJINGBAOHU“SHIERWU”GUIHUA》,GUIHUAYAOQIUJIAQIANGHUIFAXINGYOUJIWURANWUHEYOUDUFEIQIKONGZHI,KAIZHANHUIFAXINGYOUJIWURANWUHEYOUDUFEIQIJIANCE,WANSHANZHONGDIANXINGYEWURANWUPAIFANGBIAOZHUN。2013NIANGUOWUYUANFABU《DAQIWURANFANGZHIXINGDONGJIHUA》,MINGQUEYAOQIUTUIJINVOCsWURANZHILI。ZAISHIHUA、YOUJIHUAGONG、BIAOMIANTUZHUANG、BAOZHUANGYINSHUADENGXINGYESHISHIVOCsZONGHEZHENGZHI,ZAISHIHUAXINGYEKAIZHAN“XIELOUJIANCEYUXIUFU”JISHUGAIZAO。XIANSHIWANCHENGJIAYOUZHAN、CHUYOUKU、YOUGUANCHEDEYOUQIHUISHOUZHILI,ZAIYUANYOUCHENGPINYOUMATOUJIJIKAIZHANYOUQIHUISHOUZHILI。WANSHANTULIAO、JIAOZHANJIDENGCHANPINHUIFAXINGYOUJIWUXIANZHIBIAOZHUN,TUIGUANGSHIYONGSHUIXINGTULIAO,GULISHENGCHAN、XIAOSHOUHESHIYONGDIDU、DIHUIFAXINGYOUJIRONGJI。2016NIANGUOWUYUANFABULE《“SHISANWU”SHENGTAIHUANJINGBAOHUGUIHUA》,SHOUCIJIANGZHONGDIANDIQUZHONGDIANXINGYEHUIFAXINGYOUJIWULIEWEIGUOJIAWURANWUPAIFANGZONGLIANGKONGZHIZHIBIAO。HUANBAOBUYU2012NIANFABULE《ZHONGDIANQUYUDAQIWURANFANGZHI“SHIERWU”GUIHUA》,YAOQIUKAIZHANZHONGDIANXINGYEZHILI,WANSHANHUIFAXINGYOUJIWUWURANFANGZHITIXI。2013NIANHUANBAOBUHUANYINFALE《HUIFAXINGYOUJIWU(VOCs)WURANFANGZHIJISHUZHENGCE》,TICHULESHENGCHANVOCsWULIAOHEHANVOCsCHANPINDESHENGCHAN、CHUCUNYUNSHUXIAOSHOU、SHIYONG、XIAOFEIGEHUANJIEDEWURANFANGZHICELVEHEFANGFA。2014NIANHUANBAOBUBANBU《SHIHUAXINGYEHUIFAXINGYOUJIWUZONGHEZHENGZHIFANGAN》,LVXIANKAIZHANSHIHUAXINGYEDEVOCsZHILIGONGZUO。2015NIANHUANBAOBU、CAIZHENGBU、GUOJIAFAGAIWEIYINFALE《HUIFAXINGYOUJIWUPAIWUSHOUFEISHIDIANBANFA》,ZAISHIYOUHUAGONGXINGYEHEBAOZHUANGYINSHUAXINGYESHIDIANVOCsPAIWUFEIDEZHENGSHOUGONGZUO。WOGUOBANBUDEYOUGUANVOCsWURANFANGZHIDEZHUYAOZHENGCEJIANBIAO1。

       WOGUOXIANXINGDE《HUANJINGKONGQIZHILIANGBIAOZHUN》(GB3095—2012)ZHONGWEISHEJIVOCs,《SHINEIKONGQIZHILIANGBIAOZHUN》(GB/T18883—2002)、《CHENGYONGCHENEIKONGQIZHILIANGPINGJIAZHINAN》(GB/T27630—2011)JINSHEJILESHAOLIANGDEVOCsZHIBIAO,ZHUYAOBAOKUOBEN、JIABEN、ERJIABEN、ZONGHUIFAXINGYOUJIWUDENG。ZAIWURANWUPAIFANGBIAOZHUNFANGMIAN《DAQIWURANWUZONGHEPAIFANGBIAOZHUN》(GB1297—1996)ZHONGDUIYUVOCsKONGZHI,ZHUYAOJIZHONGZAIBEN、JIABEN、ERJIABEN、LVBENJIZHONGZHIBIAO,YIJIVOCsHEFEIJIAWANZONGJINGDENGZONGLIANGZHIBIAO。ZAI《ECHOUWURANWUPAIFANGBIAOZHUN》(GB14554—93)ZHONGDUICHANGJIEECHOUWURANWU(ZHUYAOWEIYOUJIHANLIUHUAHEWU)PAIFANGNONGDUZHIDINGLEXIANZHI;CIWAIZAI《SHIYOUHUAXUEGONGYEWURANWUPAIFANGBIAOZHUN》(GB31571—2015)、《SHAOJIAN、JULVYIXIGONGYEWURANWUPAIFANGBIAOZHUN》(GB31572—2015)、《HECHENGGEYURENZAOGEGONGYEWURANWUPAIFANGBIAOZHUN》(GB21902—2009)、《CHUYOUKUDAQIWURANWUPAIFANGBIAOZHUN》(GB20950—2007)、《JIAYOUZHANDAQIWURANWUPAIFANGBIAOZHUN》(GB20952-2007)DENGYIXILIEXINGYEPAIFANGBIAOZHUN,YEDUIYIXIEXINGYETEZHENGWURANWUPAIFANGXIANZHIJINXINGLEGUIDING。CONGVOCsXIANGMUSHEZHISHANGLAIKAN,ZHUYAOCEZHONGYUQIDUIYURENTIJIANKANGHEHUANJINGDEZHIJIEWEIHAI,ERDUIYUZUOWEIO3ZHONGYAOQIANTIWUDEYIXILIETANQINGHUAHEWU、QUAN、TONGLEIYOUJIWUHUANMEIYOUZUGOUDEZHONGSHI。WOGUOBANBUDEVOCsWURANKONGZHIBIAOZHUNHEHUANJINGZHILIANGBIAOZHUNJIANBIAO2。

手机捕鱼        WOGUOMUQIANDEVOCsBIAOZHUNFENXIFANGFAJUNWEILIXIANFANGFA,FEIQIZHONGDEVOCsDUOCAIYONGZHENTONGHUOQIDAICAIYANG,HUANJINGKONGQIZEDADUOSHIZHENTONG、QIDAI、CAIYANGGUANCAIJIHUOGUTIXIFUJIXIFUCAIYANG,RANHOUJIANGYANGPINSONGHUISHIYANSHICAIYONGQIXIANGSEPUFAHUOSHIQIXIANGSEPUZHIPULIANYONGFAJINXINGFENXI。MUQIAN,DUIYUHUANJINGKONGQIHEFEIQIZHONGVOCsDEZAIXIANJIANCEFANGFASHANGMEIYOUXINGCHENGGUOJIABIAOZHUNFANGFA。WOGUOBANBUDEVOCsXIANGGUANJIANCEFENXIFANGFABIAOZHUNJIANBIAO3。

我國環境空氣中VOCs監測情況

手机捕鱼        WOGUOGUOJIAHUANJINGKONGQIZHILIANGJIANCEWANG(YIXIAJIANCHENG“GUOJIAWANG”)YU2013NIANQUANMIANJIANCHENGBINGTOURUYUNXING,GUOJIAWANGHANGAILEQUANGUO31GESHENGQUSHIDE338GEDIJIYISHANGCHENGSHIDE1436GEZHANDIAN,MUQIANGUOJIAWANGNEISUOYOUZHANDIANQUANBUANZHAO《HUANJINGKONGQIZHILIANGBIAOZHUN》(GB3095—2012)DEYAOQIUKAIZHANLESO2、NO2、CO、O3、PM10、PM2.5DEJIANCE,DANYOUYUGUOJIAHUANJINGKONGQIZHILIANGBIAOZHUNWEIDUIHUANJINGZHONGVOCsDENONGDUXIANZHIZUOCHUGUIDING,YINCIGUOJIAWANGNEIBINGMEIYOUQUANMIANKAIZHANVOCsDEJIANCEGONGZUO。MUQIAN,GUOJIAWANGNEIJINYOUGUOJIADAQIBEIJINGZHANSHANDONGCHANGDAOZHANKAIZHANLEVOCsDEZAIXIANJIANCE,JIANCEXIANGMUZHUYAOWEIC2—C12FANWEINEIDEWANJING、XIJING、FANGXIANGJINGDENGO3QIANTIWU。

手机捕鱼        2016NIANHUANBAOBUZAIJINGJINJIJIZHOUBIANQUYU(BEIJING、TIANJIN、HEBEI、SHANDONG、HENAN)ZUJIANLEKELIWUZUFENHEGUANGHUAXUEJIANCEWANG,GAIWANGZHUYAOYOUJINGJINJIJIZHOUBIANQUYUXIANYOUCHENGSHIZHANHEQUYUZHANZHONGJUBEIJIANCENENGLIHETIAOJIANDEBUFENZHANDIANZUCHENG,GONGBAOKUO19GEZIDONGJIANCEZHANDIANHE23GESHOUGONGJIANCEZHANDIAN,ZAIKAIZHANKONGQIZHILIANGCHANGGUICANSHUJIANCEDEJICHUSHANG,KAIZHANLEKELIWUHUAXUEZUFENDEZAIXIANJIANCEHUOSHOUGONGJIANCE、FEIJIAWANZONGJING(NMHCs)、GUOYANGXIANJIXIAOSUANZHI(PANs)、HUIFAXINGYOUJIWU(VOCs)、QIXIANGCANSHUDENGYANJIUXINGJIANCE。CHUCIZHIWAI,QIYUDABUFENCHENGSHISHANGWEIQUANMIANKAIZHANVOCsJIANCE。

手机捕鱼        JINNIANLAIBUFENDIQUHUANBAOBUMEN、KEYANJIGOUHEGAODENGYUANXIAOZHENDUIVOCsKAIZHANLEYIXIESHIYANXINGJIANCE。YOUYANJIU[3-8]XIANSHIBUTONGQUYUVOCsZHONGLEIHEZUCHENGSUIRANCUNZAIYIDINGDECHAYI,DANYIBANLAISHUO,WANJING、FANGXIANGJING、LUDAIJING、XIJING、GUIJING、QUANLEI、TONGLEISHIGEDIPUBIANCUNZAIDEVOCs,BINGQIEGELEIVOCsZHONGDUIO3SHENGCHENGYINGXIANGJIAODADEZHUYAOSHIFANGXIANGJINGHEXIJING。QIZHONGZAISHANGHAIJIANCEDAODEVOCsBAOKUODINGWAN、BINGWAN、YIWAN、BENXIWU、2-JIAJIWUWAN、1,2-ERLVYIWANDENG,QINONGDUSHUIPINGZAI1.10~8.41ppbZHIJIAN;ZAIBEIJINGJIANCEDAODEVOCsBAOKUOYIGUI、YIWAN、BINGWAN、BENXIWU、YIXI、ZHENG/YIDINGWAN、YIWUWANDENG,QINONGDUSHUIPINGZAI1.12~5.25ppbZHIJIAN。

手机捕鱼        ZHONGGUOHUANJINGJIANCEZONGZHANDAQIJIANCESHIYANSHIYU2012NIAN5YUEZAIBEIJINGDUIHUANJINGKONGQIZHONGDEVOCsDENGO3QIANTIWUJINXINGLESHIYANJIANCE。VOCsJIANCESHEBEICAIYONGTH—PKU—300XINGHUIFAXINGYOUJIWUKUAISUZAIXIANJIANCEXITONG,GAIJIANCEXITONGCAIYONGCHAODIWENYUNONGSUOYUQIXIANGSEPU—ZHIPULIANYONG(GC—MS)JIANCEJISHU,QIGC—MSCAIYONGQP2010EXINGGC—MS,CELIANGDUIXIANGHANGAILEMEIGUOEPAGUANGHUAXUEPINGGUJIANCETIXIGUIDINGDE56ZHONGO3QIANTIWU,28ZHONGLUDAIJINGHE15ZHONGHANYANGHUIFAXINGYOUJIWU[。JIANCEJIEGUOXIANSHISHIYANQIJIANSHIYANDIANWEIZHOUWEIHUANJINGKONGQIZHONGNONGDUJIAOGAODEVOCsZHUYAOBAOKUO:YIWAN、ZHENGDINGWAN、BINGTONG、YIXI、BINGWAN、JIABEN、BEN、YIGUI、YIWUWAN、JIAN/DUIERJIABENDENG,SHIYANQIJIANHUANJINGKONGQIZHONGBUFENHUIFAXINGYOUJIWUNONGDUSHUIPINGZAI0.82~6.94ppbZHIJIAN,QINONGDUSHUIPINGYUCANKAOWENXIANZHONGDEYANJIUJIEGUOJIEJIN。

我國污染源VOCs排放監測情況

       JINLIANGNIANLAIWOGUOZHUBUDUISHAOLIANGGUOKONGQIYEKAIZHANFEIQIZHONGVOCsJIANDUXINGJIANCE,VOCsPAIFANGSHEJIDEKONGZHIBIAOZHUNBAOKUODAQIWURANWUZONGHEPAIFANGBIAOZHUN,SHIYOUJIAGONG、SHIYOULIANZHI、LIANJIAO、XIANGJIAOZHIPIN、YAGANG、HECHENGGEDENGXINGYEPAIFANGBIAOZHUN,YIJIBUFENDIQUDEDIFANGBIAOZHUN。JIANCEXIANGMUBAOKUOTVOC、2-DINGTONG、BEN、JIABEN、ERJIABEN、JIABENJIERJIABEN、BENXIWU、BINGXIJING、BINGXIQUAN、FEIJIAWANZONGJING、JIACHUN、JIALIUCHUN、JIAQUAN、LVBENLEI、LVYIXI、YIQUANDENGGONGJI23XIANG,JIANCEPINCIYOUGEDIZIXINGZHANGWO。

手机捕鱼        2016NIANKAIZHANJIANDUXINGJIANCEDEFEIQIGUOKONGQIYEGONGJI422JIA(CANYUDABIAOPINGJIADEYOU371JIAQIYE),JIANCEXINGYEHANGAIHUAGONG、TONGXINSHEBEIJIQITADIANZISHEBEIZHIZAO、YIYAOZHIZAO、JIAOTONGYUNSHUSHEBEIZHIZAO、SHIYOUJIAGONGYULIANJIAODENG28GEXINGYE。JIANCEQUYUHANGAIJIANGSU、GUANGDONG、ZHONGQING、ZHEJIANG、SHANXIDENG26GEDIQU。

       2016NIANJIANCEJIEGUOXIANSHI,FEIQIYOUZUZHIPAIFANGZHONG,90JIAQIYEBENNONGDUFANWEIWEI0.0015~10.6HAOKE/MI3,JUNDIYUZHIXINGDEPAIFANGXIANZHI;95JIAQIYEJIABENNONGDUFANWEIWEI0.001~38.5HAOKE/MI3,JUNDIYUZHIXINGDEPAIFANGXIANZHI;73JIAQIYEERJIABENNONGDUFANWEIWEI0.0015~55.9HAOKE/MI3,JUNDIYUZHIXINGDEPAIFANGXIANZHI;164JIAQIYEFEIJIAWANZONGJINGNONGDUFANWEIWEI0.03~4390HAOKE/MI3,QIZHONG3JIAQIYENONGDUCHAOGUO120HAOKE/MI3DENONGDUXIANZHI,FENBIEWEI232HAOKE/MI3、811HAOKE/MI3HE4390HAOKE/MI3。

       FEIQIWUZUZHIPAIFANGZHONG,18JIAQIYEBENNONGDUFANWEIWEI0.00025~0.15HAOKE/MI3,20JIAQIYEJIABENNONGDUFANWEIWEI0.00025~0.166HAOKE/MI3,12JIAQIYEERJIABENNONGDUFANWEIWEI0.00025~0.0199HAOKE/MI3,35JIAQIYEFEIJIAWANZONGJINGNONGDUFANWEIWEI0.02~2.86HAOKE/MI3,JUNDIYUZHIXINGDEPAIFANGXIANZHI。

結論

       MUQIAN,WOGUODEGUANGHUAXUEYANWUWURANWENTIRIYIXIANXIAN,VOCsZUOWEIDAOZHIGUANGHUAXUEYANWUWURANDEZHONGYAOQIANTIWU,JIXUQUANMIANKAIZHANHUANJINGKONGQIZHONGDEVOCsDELIXINGJIANCE。MUQIANDEYANJIUXINGJIANCEJIEGUOXIANSHIGEDIJIANCHUDEVOCsZHUYAOBAOKUOWANJING、FANGXIANGJING、LUDAIJING、XIJING、GUIJING、QUANLEI、TONGLEIDENG,QINONGDUSHUIPINGYIBANDIYU10ppb。KAOLVDAOGEDIVOCsDEWURANTEZHENGCUNZAIYIDINGCHAYI,GEDIYINGZHENDUISHIJIQINGKUANGZHIDINGCHUYOUXIANKONGZHIVOCsQINGDANBINGKAIZHANLIXINGJIANCE。

手机捕鱼        DUIGUOJIAZHONGDIANJIANKONGWURANYUANDEVOCsPAIFANGJIANCEJIEGUOBIAOMING,DABUFENGUOKONGZHONGDIANWURANYUANQIVOCsPAIFANGNONGDUMANZUGUOJIAXIANGGUANBIAOZHUNYAOQIU,DANGUOKONGQIYEMINGDANZHONGSHEVOCsQIYESHIFENYOUXIAN,DALIANGDESHEVOCsPAIFANGDEZHONGXIAOXINGWURANYUANSHANGWEINARUGUOKONGQIYEMINGDAN,YINCIGEDIXUGENJUSHIJIQINGKUANGQUEDINGSHEVOCsDEZHONGDIANJIANKONGQIYEMINGLUBINGJINKUAIKAIZHANJIANDUXINGJIANCE。

手机捕鱼        ZAIJIANCEFANGFABIAOZHUNFANGMIAN,JIXUZHIDINGWOGUOHUANJINGKONGQIZHONGVOCsYIJIWURANYUANPAIFANGVOCsDEZAIXIANJIANCEFANGFABIAOZHUN,TONGSHIPEITAOJIAKUAIVOCsBIAOZHUNYANGPINYANJIUHEVOCsJIANCEZHIKONGJISHUGUIFANYANJIU,QIANGHUAVOCsJIANCEDEZHILIANGKONGZHI,QUEBAOJIANCEZHILIANG,WEIVOCsWURANKONGZHITIGONGYOULIDEJISHUZHICHENG。


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